Increase in Hardness and Corrosion Resistance of a Medium-Carbon Steel Surface Using Cathodic Plasma Electrolytic Nitriding

IF 1.1 Q4 ELECTROCHEMISTRY Surface Engineering and Applied Electrochemistry Pub Date : 2022-08-29 DOI:10.3103/S106837552204010X
S. A. Kusmanov, I. V. Tambovskii, S. S. Korableva, S. A. Silkin, A. A. Smirnov, I. A. Kusmanova, I. S. Gorokhov
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引用次数: 1

Abstract

The structural phase composition and some properties of a modified medium-carbon steel 45 surface after being subjected to cathodic plasma electrolytic nitriding in ammonium chloride and ammonia solution were studied. It was shown that the steel surface cathodic nitriding is accompanied with a high-temperature oxidation along with formation of FeO, Fe2O3, and Fe3O4 oxides, as well as nitrogen diffusion and quenching with formation of FeN, Fe3N, and Fe4N phases, martensite, and residual austenite. A competitive effect was revealed of the surface erosion resulting from the discharges and high-temperature oxidation on the morphology and surface roughness. It was found that the maximum microhardness of the modified layer reaches 1040 HV, and the current density of the nitrided surface corrosion decreases by 1.5–2.4 times.

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阴极等离子体电解渗氮提高中碳钢表面硬度和耐蚀性
研究了改性中碳钢45表面在氯化铵和氨溶液中阴极等离子体电解渗氮后的组织、相组成和某些性能。结果表明:钢表面阴极渗氮过程伴随着高温氧化,形成FeO、Fe2O3和Fe3O4氧化物;氮的扩散和淬火,形成FeN、Fe3N和Fe4N相、马氏体和残余奥氏体。放电和高温氧化引起的表面侵蚀对表面形貌和粗糙度有竞争效应。结果表明,改性层的显微硬度最高可达1040 HV,氮化表面腐蚀电流密度降低1.5 ~ 2.4倍。
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来源期刊
Surface Engineering and Applied Electrochemistry
Surface Engineering and Applied Electrochemistry Engineering-Industrial and Manufacturing Engineering
CiteScore
1.70
自引率
22.20%
发文量
54
审稿时长
6 months
期刊介绍: Surface Engineering and Applied Electrochemistry is a journal that publishes original and review articles on theory and applications of electroerosion and electrochemical methods for the treatment of materials; physical and chemical methods for the preparation of macro-, micro-, and nanomaterials and their properties; electrical processes in engineering, chemistry, and methods for the processing of biological products and food; and application electromagnetic fields in biological systems.
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