{"title":"Kinetic Features of the Radical Polymerization of Methyl Methacrylate under Conditions of Nitroxide-Mediated Reversible Inhibition","authors":"M. Yu. Zaremski, V. V. Odintsova","doi":"10.1134/S1811238221010069","DOIUrl":null,"url":null,"abstract":"<p>This review summarizes our and published data on the kinetics and mechanism of controlled radical polymerization of methacrylates mediated by nitroxide radicals. The reasons influencing the possibility or impossibility of the realization of radical polymerization of methyl methacrylate in the mode of reversible inhibition are analyzed. The main factors determining the specificity of the nitroxide-mediated polymerization of methacrylates are the interaction of nitroxides with growing radicals by the disproportionation mechanism, the Fischer hypereffect, a high rate of reinitiation, and an abnormally low rate of reversible termination.</p>","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":"63 1","pages":"11 - 28"},"PeriodicalIF":1.6000,"publicationDate":"2021-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series C","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S1811238221010069","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
This review summarizes our and published data on the kinetics and mechanism of controlled radical polymerization of methacrylates mediated by nitroxide radicals. The reasons influencing the possibility or impossibility of the realization of radical polymerization of methyl methacrylate in the mode of reversible inhibition are analyzed. The main factors determining the specificity of the nitroxide-mediated polymerization of methacrylates are the interaction of nitroxides with growing radicals by the disproportionation mechanism, the Fischer hypereffect, a high rate of reinitiation, and an abnormally low rate of reversible termination.
期刊介绍：
Polymer Science, Series C (Selected Topics) is a journal published in collaboration with the Russian Academy of Sciences. Series C (Selected Topics) includes experimental and theoretical papers and reviews on the selected actual topics of macromolecular science chosen by the editorial board (1 issue a year). Submission is possible by invitation only. All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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