{"title":"Study of fast reactions in solution using a dielectric-heating relaxation technique","authors":"K. J. Ivin, J. McGarvey, E. Simmons","doi":"10.1039/TF9716700097","DOIUrl":null,"url":null,"abstract":"A microwave-pulse temperature-jump relaxation technique is described. Temperature rises of about 0.5 K may be produced in non-polar solvent media in about 1 µs. Spectrophotometric detection is used to monitor the resulting chemical relaxation. A conductimetric detection system is also described and applied to the measurement of relaxation times in the millisecond range in an aqueous solution.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"67 1","pages":"97-103"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716700097","citationCount":"6","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716700097","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 6
Abstract
A microwave-pulse temperature-jump relaxation technique is described. Temperature rises of about 0.5 K may be produced in non-polar solvent media in about 1 µs. Spectrophotometric detection is used to monitor the resulting chemical relaxation. A conductimetric detection system is also described and applied to the measurement of relaxation times in the millisecond range in an aqueous solution.
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