Shear viscoelastic relaxation of a nitrate melt

G. Glover, A. J. Matheson
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引用次数: 15

Abstract

The viscoelastic behaviour of a melt containing 62 mol % KNO3 and 38 mol % Ca(NO3)2 has been studied between 330 and 450 K using shear waves of frequencies 75 and 160 kHz and 5 and 30 MHz. The relaxation mechanism does not change over this range of temperature and frequency. Results may be described by a viscoelastic analogue of the Cole-Davidson expression for dielectric relaxation. This relationship also fits other common forms of viscoelastic behaviour such as that described by Barlow, Erginsav and Lamb.
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硝酸熔体的剪切粘弹性松弛
用频率为75和160 kHz、5和30 MHz的剪切波,研究了含有62 mol % KNO3和38 mol % Ca(NO3)2的熔体在330和450 K之间的粘弹性行为。松弛机制在这个温度和频率范围内不会改变。结果可以用介电弛豫的Cole-Davidson表达式的粘弹性模拟来描述。这种关系也适用于其他常见形式的粘弹性行为,如Barlow, Erginsav和Lamb所描述的。
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