{"title":"E.m.f. studies of electrolytic dissociation. Part 11.—The bisulphate ion at 25°C","authors":"C. E. Evans, C. Monk","doi":"10.1039/TF9716702652","DOIUrl":null,"url":null,"abstract":"A Pt,H2—AgCl,Ag e.m.f. cell is described whereby accurate measurements may be obtained from additions of stock solutions. Measurements with HCl + H2SO4 mixtures are used to evaluate the dissociation constant of the HSO–4 ion at 25°C. A method of extrapolation is described which aims at reducing uncertainties due to the ion size parameter. Some previous measurements with e.m.f. cells are also re-examined.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"67 1","pages":"2652-2658"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716702652","citationCount":"4","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716702652","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 4
Abstract
A Pt,H2—AgCl,Ag e.m.f. cell is described whereby accurate measurements may be obtained from additions of stock solutions. Measurements with HCl + H2SO4 mixtures are used to evaluate the dissociation constant of the HSO–4 ion at 25°C. A method of extrapolation is described which aims at reducing uncertainties due to the ion size parameter. Some previous measurements with e.m.f. cells are also re-examined.
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