{"title":"Equilibrium properties of polar gases. Part 2.—The second dielectric virial coefficients of some polar gases","authors":"A. N. Barnes, L. E. Sutton","doi":"10.1039/TF9716702915","DOIUrl":null,"url":null,"abstract":"The second dielectric virial coefficients ℬ for five polar gases CHF3, CHF2Cl, CH3Cl, CH2:CF2 and (CH3)2O were measured at 30, 50 and 70°C. for the gases CF3Cl and CF2Cl2, ℬ was measured at 50°C only. The experimental results were compared with those predicted by the forms of intermolecular potential that have been suggested for polar gases. None of these proves to be entirely satisfactory.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"160 1","pages":"2915-2925"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716702915","citationCount":"6","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716702915","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 6
Abstract
The second dielectric virial coefficients ℬ for five polar gases CHF3, CHF2Cl, CH3Cl, CH2:CF2 and (CH3)2O were measured at 30, 50 and 70°C. for the gases CF3Cl and CF2Cl2, ℬ was measured at 50°C only. The experimental results were compared with those predicted by the forms of intermolecular potential that have been suggested for polar gases. None of these proves to be entirely satisfactory.
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