{"title":"Reactions of cyanogen radicals with hydrocarbons","authors":"G. Bullock, R. Cooper","doi":"10.1039/TF9716703258","DOIUrl":null,"url":null,"abstract":"The gas-phase radiolysis of C2N2+ argon mixtures has been used as a means of following CN radical reactions with a number of hydrocarbons. Rate constants for the reaction with ethylene, propylene, 1,3-butadiene and benzene approach the collisional limit and reflect the extremely electrophilic nature of CN radicals. Rate constants for hydrogen abstraction from methane and ethane have also been determined and enable comparisons to be made with halogen atom reactions.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"67 1","pages":"3258-3264"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716703258","citationCount":"8","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716703258","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 8
Abstract
The gas-phase radiolysis of C2N2+ argon mixtures has been used as a means of following CN radical reactions with a number of hydrocarbons. Rate constants for the reaction with ethylene, propylene, 1,3-butadiene and benzene approach the collisional limit and reflect the extremely electrophilic nature of CN radicals. Rate constants for hydrogen abstraction from methane and ethane have also been determined and enable comparisons to be made with halogen atom reactions.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
