{"title":"Radiative lifetimes for the A2Σ+ (v′ = 0–7) and D2Σ+ (v′ = 0–5) Rydberg states of NO","authors":"A. M. Velasco, I. Martín *, C. Lavín, E. Bustos","doi":"10.1080/00268970500052296","DOIUrl":null,"url":null,"abstract":"Intensities for the γ(A2Σ+ → X2Π), ε(D2Σ+ → X2Π) and (D2Σ+ → A2Σ+) bands for NO have been calculated using the Molecular Quantum Defect Orbital (MQDO) methodology. Radiative lifetimes for the A2Σ+ and D2Σ+ vibrational Rydberg states have also been determined. The present results are in excellent accord with measurements available in the literature. Additionally, predictions for a number of unknown intensities and radiative lifetimes are made, given their potential usefulness.","PeriodicalId":18817,"journal":{"name":"Molecular Physics","volume":"103 1","pages":"1375 - 1385"},"PeriodicalIF":1.8000,"publicationDate":"2005-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1080/00268970500052296","citationCount":"5","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Molecular Physics","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/00268970500052296","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 5
Abstract
Intensities for the γ(A2Σ+ → X2Π), ε(D2Σ+ → X2Π) and (D2Σ+ → A2Σ+) bands for NO have been calculated using the Molecular Quantum Defect Orbital (MQDO) methodology. Radiative lifetimes for the A2Σ+ and D2Σ+ vibrational Rydberg states have also been determined. The present results are in excellent accord with measurements available in the literature. Additionally, predictions for a number of unknown intensities and radiative lifetimes are made, given their potential usefulness.
期刊介绍：
Molecular Physics is a well-established international journal publishing original high quality papers in chemical physics and physical chemistry. The journal covers all experimental and theoretical aspects of molecular science, from electronic structure, molecular dynamics, spectroscopy and reaction kinetics to condensed matter, surface science, and statistical mechanics of simple and complex fluids. Contributions include full papers, preliminary communications, research notes and invited topical review articles.
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