The Influence of Oleic Acid to Metal Nitrate Ratio on the Particle Size and Magnetic Properties of Lanthanum Ferrite Nanoparticles by Emulsion Method

IF 4.7 2区 材料科学 Q2 ENGINEERING, MANUFACTURING Materials and Manufacturing Processes Pub Date : 2011-01-31 DOI:10.1080/10426914.2010.512818
J. Chandradass, D. Bae, M. Balasubramanian, Ki Hyeon Kim
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引用次数: 6

Abstract

LaFeO3 nanoparticles of different sizes are prepared by varying the molar concentration of oleic acid to metal nitrate using emulsion combustion method. X-ray diffraction analysis confirms that LaFeO3 nanoparticles are crystalline in nature with an orthorhombic structure. The average particle size and saturation magnetization decreases from 56 to 32 nm and 0.20 to 0.08 emu/g, as molar concentration of oleic acid to metal nitrate increases from 0.25 to 1. The Fourier transform infrared (FTIR) spectra show the lower frequency bands are assigned to Fe–O stretching vibration (579 cm−1) and O–Fe–O deformation vibration (475 and 400 cm−1). The experimental results suggest that molar concentration of oleic acid to metal nitrate plays an important role in the particle size and magnetic property of combustion synthesized lanthanum ferrite nanoparticles.
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油酸与金属硝酸盐配比对乳液法制备铁酸镧纳米粒子粒径及磁性能的影响
采用乳化液燃烧法,通过改变油酸与硝酸金属的摩尔浓度,制备了不同尺寸的LaFeO3纳米颗粒。x射线衍射分析证实了LaFeO3纳米颗粒的结晶性质,具有正交结构。当油酸对硝酸金属的摩尔浓度从0.25增加到1时,平均粒径和饱和磁化强度从56减小到32 nm,从0.20 emu/g减小到0.08 emu/g。傅里叶变换红外光谱(FTIR)表明,较低的频段分配给Fe-O拉伸振动(579 cm−1)和O-Fe-O变形振动(475 cm−1和400 cm−1)。实验结果表明,油酸对金属硝酸盐的摩尔浓度对燃烧合成的铁酸镧纳米颗粒的粒径和磁性能有重要影响。
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来源期刊
Materials and Manufacturing Processes
Materials and Manufacturing Processes 工程技术-材料科学:综合
CiteScore
9.00
自引率
22.90%
发文量
132
审稿时长
3.4 months
期刊介绍: Materials and Manufacturing Processes deals with issues that result in better utilization of raw materials and energy, integration of design and manufacturing activities requiring the invention of suitable new manufacturing processes and techniques, unmanned production dependent on efficient and reliable control of various processes including intelligent processing, introduction of new materials in industrial production necessitating new manufacturing process technology, and more. Information is offered in various formats, including research articles, letter reports, review articles, conference papers, applied research, book and conference reviews, and entire issues devoted to symposia. All submitted manuscripts are subject to initial appraisal by the Editors, and, if found suitable for further consideration, to peer review by independent, anonymous expert referees. All peer review is single blind and submission is online via ScholarOne Manuscripts.
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