Metal-Organic Frameworks for Photocatalytic Water Splitting and CO2 Reduction

IF 16.1 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Angewandte Chemie International Edition Pub Date : 2023-01-23 DOI:10.1002/anie.202217565
Kang Sun, Yunyang Qian, Prof.?Dr. Hai-Long Jiang
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引用次数: 48

Abstract

Photocatalytic water splitting and carbon dioxide (CO2) reduction provide promising solutions to global energy and environmental issues. In recent years, metal-organic frameworks (MOFs), a class of crystalline porous solids featuring well-defined and tailorable structures as well as high surface areas, have captured great interest toward photocatalytic water splitting and CO2 reduction. In this review, the semiconductor-like behavior of MOFs is first discussed. We then summarize the recent advances in photocatalytic water splitting and CO2 reduction over MOF-based materials and focus on the unique advantage of MOFs for clarifying the structure-property relationship in photocatalysis. In addition, some representative characterization techniques have been presented to unveil the photocatalytic kinetics and reaction intermediates in MOF-based systems. Finally, the challenges, and perspectives for future directions are proposed.

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光催化水裂解和CO2还原的金属-有机框架
光催化水分解和二氧化碳(CO2)还原为全球能源和环境问题提供了有前途的解决方案。近年来,金属有机骨架(mof)是一类具有良好定义和可定制结构以及高表面积的晶体多孔固体,在光催化水分解和二氧化碳还原方面引起了人们的极大兴趣。本文首先讨论了mof的半导体性质。总结了mof基材料在光催化水分解和CO2还原方面的最新进展,重点介绍了mof在阐明光催化结构-性能关系方面的独特优势。此外,还提出了一些具有代表性的表征技术来揭示mof基体系的光催化动力学和反应中间体。最后,提出了面临的挑战和未来的发展方向。
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来源期刊
CiteScore
26.60
自引率
6.60%
发文量
3549
审稿时长
1.5 months
期刊介绍: Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.
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