Electrochemical Corrosion of Iron Magnesium Aluminate Spinel and Lanthanum Chromite in Molten Potassium Sulfate

IF 3.8 3区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS Journal of the American Ceramic Society Pub Date : 1981-01-01 DOI:10.1111/j.1151-2916.1981.tb09532.x
Gregory A. Kaiser, John W. Halloran
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Abstract

Iron magnesium aluminate spinel and lanthanum chromite specimens are unaffected by immersion in molten K2SO4 in the absence of an electrical current, but are aggressively attacked in the presence of a direct current. Anodes are deteriorated by surface reactions, while cathodes are disintegrated due to enhanced salt penetration without gross chemical reactions.

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铝酸铁镁尖晶石和铬铁矿在硫酸钾熔液中的电化学腐蚀
铝酸铁镁尖晶石和铬酸镧试样在没有电流的情况下不受熔融K2SO4的影响,但在有直流电的情况下会受到猛烈的攻击。阳极由于表面反应而恶化,而阴极由于盐渗透增强而分解,没有明显的化学反应。
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来源期刊
Journal of the American Ceramic Society
Journal of the American Ceramic Society 工程技术-材料科学:硅酸盐
CiteScore
7.50
自引率
7.70%
发文量
590
审稿时长
2.1 months
期刊介绍: The Journal of the American Ceramic Society contains records of original research that provide insight into or describe the science of ceramic and glass materials and composites based on ceramics and glasses. These papers include reports on discovery, characterization, and analysis of new inorganic, non-metallic materials; synthesis methods; phase relationships; processing approaches; microstructure-property relationships; and functionalities. Of great interest are works that support understanding founded on fundamental principles using experimental, theoretical, or computational methods or combinations of those approaches. All the published papers must be of enduring value and relevant to the science of ceramics and glasses or composites based on those materials. Papers on fundamental ceramic and glass science are welcome including those in the following areas: Enabling materials for grand challenges[...] Materials design, selection, synthesis and processing methods[...] Characterization of compositions, structures, defects, and properties along with new methods [...] Mechanisms, Theory, Modeling, and Simulation[...] JACerS accepts submissions of full-length Articles reporting original research, in-depth Feature Articles, Reviews of the state-of-the-art with compelling analysis, and Rapid Communications which are short papers with sufficient novelty or impact to justify swift publication.
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