Investigation of Friedel-Crafts Alkylation in the Presence of Supported Sulfonic Acid on Silica Gel

A. Kiasat, M. Karimi-Cheshmeali, R. Soleymani, H. Rajabzadeh
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引用次数: 1

Abstract

From the Reaction between cellulose and chloro sulfonic acid was prepared sulfuric acid cellulose composition as a new solid acid. The solid acid supported on silica gel and then as an effective catalyst in Friedel-Crafts alkylation of alcohols and aromatic compounds was used. The reaction progress was controlled using thin layer chromatography and the reaction products were analyzed using IR spectroscopy devise. The results show this new catalyst is effective in the friedel crafts alkylation and C-C bond formation was done in short time with very good yields.
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负载型磺酸存在下硅胶上Friedel-Crafts烷基化反应的研究
由纤维素与氯磺酸反应制得硫酸纤维素组合物作为一种新型固体酸。将固体酸负载于硅胶上,作为醇类和芳香族化合物Friedel-Crafts烷基化反应的有效催化剂。采用薄层色谱法对反应过程进行控制,并用红外光谱仪对反应产物进行分析。结果表明,该催化剂能有效地催化烷基化反应,在较短的时间内生成C-C键,收率较高。
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来源期刊
E-journal of Chemistry
E-journal of Chemistry CHEMISTRY, MULTIDISCIPLINARY-
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