Effect of Heat Treatment on Corrosion Behaviors of Mg-5Y-1.5Nd Alloys

IF 2.3 Q3 ELECTROCHEMISTRY International journal of electrochemistry Pub Date : 2016-04-19 DOI:10.1155/2016/7097589
Xiumin Ma, Q. Jiang, Yantao Li, B. Hou
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引用次数: 12

Abstract

Corrosion behavior of Mg-5Y-1.5Nd alloy was investigated after heat treatment. The microstructure and precipitation were studied by scanning electron microscope (SEM) and energy dispersive spectrometer (EDS). The weight loss rates of different samples were arranged as T6-24 hT6-6 hT6-14 has-castT4. The open circuit potential (OCP) showed that T4 sample had a more positive potential than that of other samples. The potentiodynamic polarization curves showed that the T6-24 h sample had the highest corrosion current density of 245.362 μAcm−2, whereas the T4 sample had the lowest at 52.164 μAcm−2. The EIS results confirmed that the heat treatment reduced the corrosion resistance for Mg-5Y-1.5Nd alloy, because the precipitations acted as the cathode of electrochemical reactions to accelerate the corrosion process. The corrosion rates of different samples were mainly determined by the amount and distribution of the precipitations. The precipitations played dual roles that depended on the amount and distribution. The presence of the phase in the alloys could deteriorate the corrosion performance as it could act as an effective galvanic cathode. Otherwise, a fine and homogeneous phase appeared to be a better anticorrosion barrier.
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热处理对Mg-5Y-1.5Nd合金腐蚀行为的影响
研究了Mg-5Y-1.5Nd合金热处理后的腐蚀行为。采用扫描电镜(SEM)和能谱仪(EDS)对其微观结构和析出进行了研究。不同样品的失重率按T6-24 hT6-6 hT6-14 has-castT4排列。开路电位(OCP)显示T4样品比其他样品具有更多的正电位。动电位极化曲线表明,t6 ~ 24 h试样腐蚀电流密度最高,为245.362 μAcm−2,T4试样腐蚀电流密度最低,为52.164 μAcm−2。EIS结果证实,热处理降低了Mg-5Y-1.5Nd合金的耐蚀性,因为析出物作为电化学反应的阴极,加速了腐蚀过程。不同样品的腐蚀速率主要取决于析出物的数量和分布。降水在数量和分布上具有双重作用。合金中相的存在会使合金的腐蚀性能恶化,因为它可以作为有效的电阴极。此外,细而均匀的相似乎是一个更好的防腐屏障。
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