{"title":"Preparation and Corrosion Performance of a Doping Modified Hybrid Film on Aluminum Tube","authors":"W. Tian, Rui-lin Man, Xiong Huang, F. He","doi":"10.11903/1002.6495.2013.233","DOIUrl":null,"url":null,"abstract":"A hybrid sol was prepared by sol-gel technique with precursors of ethylsilicate(TEOS)and vinyltriethoxysilane(KH151), and which then was further doped with 1.5×10-3mol/L Ce(NO3)3to get a Ce-doped hybrid sol. A coating of this Ce-doped hybrid sol was prepared on aluminum tube by dipping method. Results of bluestone drips test, neutral salt spray test and electrochemical measurement showed that the coating doping modified hybrid film possessed superior corrosion performance rather than the conventional chromate passivation film. The infrared spectrum of the coating revealed that there existed different types of Si—O—Si covalent bonds and organic functional groups C=C covalent bonds, which might enhance the hydrophobicity of the coating. Finally SEM examination showed that the formed coating was dense, uniform and smooth.","PeriodicalId":10727,"journal":{"name":"腐蚀科学与防护技术","volume":"26 1","pages":"334-338"},"PeriodicalIF":0.0000,"publicationDate":"2014-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"腐蚀科学与防护技术","FirstCategoryId":"1087","ListUrlMain":"https://doi.org/10.11903/1002.6495.2013.233","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Chemical Engineering","Score":null,"Total":0}
引用次数: 0
Abstract
A hybrid sol was prepared by sol-gel technique with precursors of ethylsilicate(TEOS)and vinyltriethoxysilane(KH151), and which then was further doped with 1.5×10-3mol/L Ce(NO3)3to get a Ce-doped hybrid sol. A coating of this Ce-doped hybrid sol was prepared on aluminum tube by dipping method. Results of bluestone drips test, neutral salt spray test and electrochemical measurement showed that the coating doping modified hybrid film possessed superior corrosion performance rather than the conventional chromate passivation film. The infrared spectrum of the coating revealed that there existed different types of Si—O—Si covalent bonds and organic functional groups C=C covalent bonds, which might enhance the hydrophobicity of the coating. Finally SEM examination showed that the formed coating was dense, uniform and smooth.
期刊介绍:
Corrosion Science and Protection Technology is approved by the General Administration of Press and Publication of the State Council, the Chinese Academy of Sciences, the Chinese Academy of Sciences Institute of Metals organized by the domestic and international public circulation of national periodicals metal surface treatment academic journals.
The journal is a professional and technical publication. It reports the scientific and technological achievements in the field of metal corrosion and protection, and publishes research reports, reviews, technical reports, research briefs, failure analysis, experience exchange, etc. The readers are engaged in the field of metal corrosion and protection. The target readers are scientific and technological personnel engaged in metal corrosion and protection and teachers and students of related professional colleges and universities.
Corrosion Science and Protection Technology is indexed in CSCD, CSTPCD, CA,MA,SA and other authoritative databases.