Effect of pH Value on Electrochemical Behavior of High Nitrogen Stainless Steel in NaCl Solution

Lixia Liu, Y. Qiao
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Abstract

The electrochemical behavior of high nitrogen stainless steel(HNS) in 1 mol/L NaCl solution with different pH values was investigated by means of potentiodynamic polarization curves, electrochemical impendence spectrum and current-time transient curves. The results show that anodic passivation of HNS could occur in alkaline solutions, while the corrosion rate of HNS decreased with the increasing pH value; a porous film might be grown on HNS in neutral NaCl solution due to the companying processes of dissolution and repassivation. In acidic and alkaline NaCl solutions, the formed passive films on HNS exhibit superior protectiveness rather than that in neutral NaCl solution.
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pH值对高氮不锈钢在NaCl溶液中电化学行为的影响
采用动电位极化曲线、电化学阻抗谱和电流-时间瞬变曲线研究了高氮不锈钢(HNS)在1 mol/L不同pH值NaCl溶液中的电化学行为。结果表明:HNS在碱性溶液中发生阳极钝化,腐蚀速率随pH值的增加而降低;在中性NaCl溶液中,由于溶蚀和再钝化的共同作用,HNS表面可能会形成多孔膜。在酸性和碱性NaCl溶液中,在HNS上形成的钝化膜表现出比在中性NaCl溶液中更好的保护作用。
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来源期刊
Corrosion Science and Protection Technology
Corrosion Science and Protection Technology Chemical Engineering-Chemical Engineering (all)
CiteScore
0.60
自引率
0.00%
发文量
2399
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