Effects of Ultrasonic Amplitude on Electrochemical Properties During Cavitation of Carbon Steel in 3.5% NaCl Solution

IF 0.8 Q4 ELECTROCHEMISTRY Corrosion Science and Technology-Korea Pub Date : 2020-01-01 DOI:10.14773/CST.2020.19.4.163
I. J. Jang, Ki Tae Kim, Y. Yoo, Young-Sik Kim
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引用次数: 2

Abstract

Cavitation corrosion in many industrial plants has recently become a serious issue. Cavitation corrosion has generally been investigated using a vibratory method based on ASTM G32 standard, and the test can be divided into direct cavitation and indirect cavitation. Cavitation corrosion test uses the vibration frequency of the horn of 20 kHz with constant peak-to-peak displacement amplitude. In this work, the peak-to-peak amplitude was controlled from 15 μm to 85 μm, and electrochemical measurements were obtained during indirect cavitation. The relationship between cavitation corrosion rate and electrochemical properties was discussed. Corrosion steps of carbon steel at the initial stage under cavitation condition in 3.5 % NaCl can be proposed. When the cavitation strength is relatively low, corrosion of the steel is more affected by the electrochemical process than by the mechanical process; but when the cavitation strength is relatively high, corrosion of the steel is affected more by the mechanical process than by the electrochemical process. This work confirmed that the critical ultrasonic amplitude of 0.42 %C carbon steel is 53.8 μm, and when the amplitude is less than 53.8 μm, the corrosion effect during the cavitation corrosion process is higher than the mechanical effect.
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超声振幅对碳钢在3.5% NaCl溶液中空化过程中电化学性能的影响
近年来,在许多工业装置中,空化腐蚀已成为一个严重的问题。空化腐蚀的研究一般采用基于ASTM G32标准的振动法,试验可分为直接空化和间接空化。空化腐蚀试验采用恒峰间位移振幅的喇叭振动频率为20khz。在间接空化过程中,将峰间振幅控制在15 μm ~ 85 μm之间,进行了电化学测量。讨论了空化腐蚀速率与电化学性能的关系。提出了在3.5% NaCl中空化条件下碳钢初始阶段的腐蚀步骤。当空化强度较低时,电化学过程对钢的腐蚀影响大于机械过程;但当空化强度较高时,钢的腐蚀受机械过程的影响大于电化学过程的影响。本工作证实了0.42% C碳钢的临界超声振幅为53.8 μm,当振幅小于53.8 μm时,空化腐蚀过程中的腐蚀效应大于机械效应。
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1.30
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66.70%
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