Corrosion Failure Analysis of Air Vents Installed at Heat Transport Pipe in District Heating System

IF 0.8 Q4 ELECTROCHEMISTRY Corrosion Science and Technology-Korea Pub Date : 2020-01-01 DOI:10.14773/CST.2020.19.4.189
Hyongjoon Lee, H. Chae, J. Cho, W. Kim, J. Jeong, Heesan Kim, Jung-Gu Kim, S. Lee
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Abstract

Two air vents situated on a heat transport pipe in district heating system were exposed to the same environment for 10 years. However, one air vent was more corroded than the other. It also had a hole on the top of the front-end pipe. Comparative analysis was performed for these air vents to identify the cause of corrosion and establish countermeasures. Through experimental observation of the damaged part and analyses of powders sampled from air vents, it was found that corrosion was initiated at the top of the front-end pipe. It then spread to the bottom. Energy dispersive X-ray spectroscopy results showed that potassium and chlorine were measured from the corroded product in the damaged air vent derived from rainwater and insulation, respectively. The temperature of the damaged air vent was maintained at 75 ~ 120 °C by heating water. Rainwater-soaked insulation around the front-end pipe had been hydrolyzed. Therefore, the damaged air vent was exposed to an environment in which corrosion under insulation could be facilitated. In addition, ion chromatography and inductively coupled plasma measurements indicated that the matrix of the damaged front-end pipe contained a higher manganese content which might have promoted corrosion under insulation.
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区域供热系统热传导管道通风口腐蚀失效分析
区域供热系统中位于热传导管道上的两个通风口在同一环境中暴露了10年。然而,一个通风口比另一个腐蚀得更严重。在前端管的顶部也有一个孔。对这些通风口进行了对比分析,以确定腐蚀原因并制定对策。通过对破损部位的实验观察和从通风口取样的粉末分析,发现腐蚀是在前端管的顶部开始的。然后扩散到底部。能量色散x射线能谱分析结果表明,从雨水和保温材料破损通风口的腐蚀产物中分别测得钾和氯。通过加热水将损坏的通风口温度维持在75 ~ 120℃。前端管道周围被雨水浸透的保温层已经水解。因此,损坏的通风口暴露在一个环境中,可以促进绝缘下的腐蚀。此外,离子色谱和电感耦合等离子体测量表明,损坏前端管的基体含有较高的锰含量,这可能促进了绝缘下的腐蚀。
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1.30
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66.70%
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