{"title":"Kristallstruktur des „supramolekularen“ Quecksilber(II)chlorid-thiocyanat- Hexamethylentetramin-Addukts Hg(SCN)2 · 2HgCl2 · 2C6H12N4","authors":"J. Pickardt, Gill-Taik Gong, D. Röleke","doi":"10.14279/DEPOSITONCE-7636","DOIUrl":null,"url":null,"abstract":"Crystals of the adduct Hg(SCN) 2 -2 HgCl 2 -2 C 6 H 12 N 4 were obtained from an aqueous solution containing 0.1 mol/l hexamethylenetetramine and 0.05 mol/l potassium thiocyanate and mercury(II) chloride. The compound crystallizes monoclinically; space group P 2 1 /n, a= 767.3(4), b=1854.7(7), c=872.5(7) pm, and β=101.48(5) o . The structure consists of a network of chains -Cl-Hg-Cl-Hg- and -(Cl-Hg-) 2 NCS-Hg-SCN-(Hg-Cl) 2 - which share common Hg atoms and form distorted hexagonal and trigonal channels. The hexamethylenetetramine molecules lie in the hexagonal channels","PeriodicalId":51215,"journal":{"name":"Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences","volume":"472 1","pages":"321-324"},"PeriodicalIF":0.8000,"publicationDate":"1994-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.14279/DEPOSITONCE-7636","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Crystals of the adduct Hg(SCN) 2 -2 HgCl 2 -2 C 6 H 12 N 4 were obtained from an aqueous solution containing 0.1 mol/l hexamethylenetetramine and 0.05 mol/l potassium thiocyanate and mercury(II) chloride. The compound crystallizes monoclinically; space group P 2 1 /n, a= 767.3(4), b=1854.7(7), c=872.5(7) pm, and β=101.48(5) o . The structure consists of a network of chains -Cl-Hg-Cl-Hg- and -(Cl-Hg-) 2 NCS-Hg-SCN-(Hg-Cl) 2 - which share common Hg atoms and form distorted hexagonal and trigonal channels. The hexamethylenetetramine molecules lie in the hexagonal channels
期刊介绍：
Zeitschrift fuer Naturforschung B (ZNB) publishes novel research in all areas of inorganic chemistry, organic chemistry, and analytical chemistry. In particular, the journal focuses on solid state chemistry, coordination chemistry, main group element chemistry, synthetic organic chemistry, natural product chemistry and, to a lesser extent, on analytical chemistry. For more than 65 years Zeitschrift fuer Naturforschung B has been open to contributions from all fields of experimental and theoretical chemistry. Zeitschrift fuer Naturforschung B publishes 12 issues per volume/year. Sometimes double issues occur.
Topics
Solid state chemistry
Coordination chemistry
Main group element chemistry
Organic chemistry
Natural product chemistry.
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