Effect of the Recycled Rubber on the Properties of Recycled Rubber/Recycled Polypropylene Blends

E. Ciro, J. Parra, M. Zapata, E. Murillo
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引用次数: 10

Abstract

This study evaluates the influence of recycled rubber (RR) with a specific particle size in the properties of blends, blended recycled polypropylene/polyethylene (RPP) and RR (RPP/RR). The proportions of RPP/RR employed to obtain the blends were as follows: 90/10 (PP90), 75/25 (PP75), 60/40 (PP60) and 45/55 (PP45). The particle size of the RR employed was 850 µm . The properties of the blends were evaluated by rheometric, thermogravimetric (TGA), differential scanning calorimetric (DSC), scanning electronic microscopy (SEM), density, melt flow index and tensile analysis. The maximum torque increased with the RPP content. By DSC analysis, it was observed that the RPP exhibited two melting temperatures, the first corresponded to low density polyethylene (LDPE) and the second to polypropylene (PP). Furthermore, the RR affected the crystallinity of the RPP. By using SEM and TGA analyses, it was determined that the RPP as well as RR contained fillers. The blend densities were higher than those of RPP. The melt flow index exhibited a trend with the amount of RR.PACS: 61.25.hk, 83.80.Va, 81.05.Lg
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再生橡胶对再生橡胶/再生聚丙烯共混物性能的影响
本研究考察了特定粒径的再生橡胶(RR)对共混物、共混再生聚丙烯/聚乙烯(RPP)和再生聚乙烯(RPP/RR)性能的影响。共混物的RPP/RR比例分别为90/10 (PP90)、75/25 (PP75)、60/40 (PP60)和45/55 (PP45)。所采用的RR粒径为850µm。通过流变学、热重法(TGA)、差示扫描量热法(DSC)、扫描电镜(SEM)、密度、熔体流动指数和拉伸分析对共混物的性能进行了评价。最大转矩随RPP含量的增加而增大。通过DSC分析发现,RPP呈现出两个熔融温度,第一个对应于低密度聚乙烯(LDPE),第二个对应于聚丙烯(PP)。此外,RR对RPP的结晶度也有影响。通过SEM和TGA分析,确定RPP和RR均含有填料。共混密度高于RPP。熔体流动指数随RR量的增加呈一定的趋势。pac: 61.25。, 83.80港元。弗吉尼亚州,81.05.Lg
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