Method for Calculation of the Current Concentration of Alkali in the Electrolyte During the Water Electrolysis Process

IF 0.4 Q4 CHEMISTRY, ANALYTICAL French-Ukrainian Journal of Chemistry Pub Date : 2021-01-01 DOI:10.17721/fujcv9i2p27-33
A. Rusanov, V. Solovey, M. Zipunnikov, V. Semikin
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Abstract

The article proposes a method for calculation of the current concentration of alkali in the electrolyte, taking into account the consumption and replenishment of feed water in the electrolyzer, which allows to estimate the specific electrical conductivity of the electrolyte during electrolysis process. This is important to increase the efficiency of the water electrolysis process. The calculated change of the current concentration of alkali in the electrolyte in high-pressure electrolyzers taking into account the volume of produced hydrogen is given. With the usage of the proposed method, it is established that the current concentrations of alkali in the electrolyte during the operation of the developed high-pressure electrolyzers are in the range of optimal concentrations, where the specific electrical conductivity of the electrolyte is close to maximum and changes according to alkali concentration change.
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电解过程中电解液中碱电流浓度的计算方法
本文提出了一种计算电解液中碱的电流浓度的方法,该方法考虑了电解槽中给水的消耗和补充,从而可以估计电解过程中电解液的比电导率。这对于提高水电解过程的效率是非常重要的。给出了考虑产氢量的高压电解槽电解液中碱电流浓度的计算变化。利用所提出的方法,确定了所研制的高压电解槽运行过程中电解液中碱的电流浓度在最佳浓度范围内,此时电解液的比电导率接近最大值,且随碱浓度的变化而变化。
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来源期刊
French-Ukrainian Journal of Chemistry
French-Ukrainian Journal of Chemistry CHEMISTRY, ANALYTICAL-
自引率
0.00%
发文量
13
审稿时长
4 weeks
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