KATALIS BIMETAL Cu-Cr/DIATOMEA UNTUK HIDROGENASI MINYAK SAWIT

Husni Husin
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引用次数: 2

Abstract

A series of bimetallic Cu-Cr supported onto diatomite was synthesized using impregnation method and characterized using X-ray diffractometer (XRD) technique. The catalyst compositions were CuCrO2, Cu2O, Al2O3 and SiO2. The catalyst contained 5, 10, 20, and 30 wt.%  of Cu-Cr respectively, with Cu : Cr ratio of 1:1. The catalytic performance of the samples was evaluated based on the application to a hydrogenated  palm oil at 70oC and 7 bar of pressure by measuring its iodine number. The result showed that the bimetallic Cu-Cr deposited onto diatomite was an effective catalysts for hydrogenation of palm oils and its catalytic activity was highly dependent on the composition of metals. Iodine number of palm oil decreased to 27.2  from 43.28 by using of 30 wt.% of Cu-Cr after 120 minutes reaction   almost similar to the performance of commercial nickel catalyst that could decrease the iodine number to 26.1. Keywords: hydrogenation, palm oil, copper-chromium, diatomite, impregnation.
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双金属催化剂Cu-Cr/硅藻土催化沙特明胶酶
采用浸渍法制备了一系列双金属Cu-Cr载体硅藻土,并用x射线衍射仪(XRD)对其进行了表征。催化剂组成为CuCrO2、Cu2O、Al2O3和SiO2。催化剂的Cu-Cr含量分别为5%、10%、20%和30wt .%, Cu: Cr比为1:1。通过测量氢化棕榈油的碘值,在70℃和7 bar压力下对样品的催化性能进行了评价。结果表明,沉积在硅藻土上的Cu-Cr双金属是棕榈油加氢的有效催化剂,其催化活性与金属组成高度相关。使用30%的Cu-Cr,反应120分钟后,棕榈油的碘值从43.28降至27.2,与商用镍催化剂的性能基本一致,可将碘值降至26.1。关键词:加氢,棕榈油,铜铬,硅藻土,浸渍。
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审稿时长
12 weeks
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