Die Reaktionen von Wolframhexachlorid mit überschüssigem 2,2-Dimethylpropylidinphosphan : die Kristallstrukturen von WCl5P2(C5H9)3, WCl4P5(C5H9)5 und [C3(C4H9)3]+[WCl5(C4H9C≡CC4H9]-
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Abstract
The reaction of tungsten hexachloride with excess 2,2-dimethylpropylidynephosphane, C 4 H 9 -C≡P, leads to the tungsten phosphaalkyne clusters WCl 5 P 2 (C 5 H 9 ) 3 and WCl 4 P 5 (C 5 H 9 ) 5 , as well as to the tris(t-butyl)cyclopropenium pentachloro tungsten alkyne complex [C 3 (C 4 H 9 ) 3 ] + [WCl 5 (C 4 H 9 C≡CC 4 H 9 )] − . All complexes were characterized by X-ray structure determinations
六氯化钨的反应2,过剩2-dimethylpropylidynephosphane, 4 H 9 C - C≡P,导致钨phosphaalkyne集群水控制法5 P 2 (C 5 H 9) 3和水控制法4 P (C 5 H 9) 5,以及三羟甲基氨基甲烷(叔丁基)cyclopropenium五氯液钨炔复杂[C 3 (C 4 H 9) 3] +[水控制法5 (4 H 9 C≡CC 4 H 9)]−。所有配合物均通过x射线结构测定进行了表征
期刊介绍：
Zeitschrift fuer Naturforschung B (ZNB) publishes novel research in all areas of inorganic chemistry, organic chemistry, and analytical chemistry. In particular, the journal focuses on solid state chemistry, coordination chemistry, main group element chemistry, synthetic organic chemistry, natural product chemistry and, to a lesser extent, on analytical chemistry. For more than 65 years Zeitschrift fuer Naturforschung B has been open to contributions from all fields of experimental and theoretical chemistry. Zeitschrift fuer Naturforschung B publishes 12 issues per volume/year. Sometimes double issues occur.
Topics
Solid state chemistry
Coordination chemistry
Main group element chemistry
Organic chemistry
Natural product chemistry.
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