Potential Application of Membrane Obtained from Sisal Bagasse in the Removal of Inhibitors from the Fermentation Process

IF 1.3 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Journal of the Brazilian Chemical Society Pub Date : 2023-10-06 DOI:10.21577/0103-5053.20230066
F. Xavier, A. Silva, M. Lima, M. D. da Fonseca, M. da Conceição
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Abstract

Annual world production of sisal is estimated to be 400,000 tons, but the processing of sisal fiber generates around 160,000 tons of waste per year. The sisal bagasse is discarded, even though it is about 60% carbohydrates in its structure. Therefore, this work seeks to add value to sisal bagasse through the production of cellulose acetate membranes aimed at removing inhibitors from the fermentation process. The membrane was developed using a cellulose acetate polymer synthesized from cellulose isolated from sisal bagasse. Alkaline and acid pre-treatments resulted in 90% pure cellulose. The obtained cellulose acetate was confirmed by infrared spectroscopy. In the synthesis of the membranes, the influence of agitation time and temperature of the bath on the selectivity and porosity were evaluated in four tests, the third condition stood out with porosity of 26.23% and selectivity of 94.51% in the removal of the furfural and 36.62% of the acetic acid.
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剑麻甘蔗渣膜在去除发酵过程中抑制剂方面的潜在应用
世界剑麻的年产量估计为40万吨,但剑麻纤维的加工每年产生约16万吨废物。剑麻甘蔗渣被丢弃,即使它的结构中含有大约60%的碳水化合物。因此,这项工作旨在通过生产旨在从发酵过程中去除抑制剂的醋酸纤维素膜来增加剑麻甘蔗渣的价值。该膜是用从剑麻甘蔗渣中分离的纤维素合成的醋酸纤维素聚合物制成的。碱性和酸性预处理可获得90%的纯纤维素。所得醋酸纤维素经红外光谱分析证实。在膜的合成过程中,考察了搅拌时间和浴槽温度对膜的选择性和孔隙率的影响,其中,第三种条件下膜的孔隙率为26.23%,糠醛的去除率为94.51%,乙酸的去除率为36.62%。
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来源期刊
CiteScore
2.90
自引率
7.10%
发文量
99
审稿时长
3.4 months
期刊介绍: The Journal of the Brazilian Chemical Society embraces all aspects of chemistry except education, philosophy and history of chemistry. It is a medium for reporting selected original and significant contributions to new chemical knowledge.
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