Influence of calcination temperature on structure and multiferroic properties of barium ferrite ceramics

IF 0.9 4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Processing and Application of Ceramics Pub Date : 2022-01-01 DOI:10.2298/pac2202106z
Zhixin Zeng, Q. Zhang, Heng Wu, Mengshuang Lan, Hongmin Ao, Wenchuan Li, Chuang Zhou, Jizhuang He, S. Xing, X. Deng, R. Gao
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Abstract

In this paper, barium ferrite powders were synthesized by sol-gel method, calcined at different temperatures, and on this basis the corresponding ceramics were prepared. The effects of calcination temperature on the structure, magnetic, dielectric and multiferroic properties of BaFe12O19 ceramics were studied. XRD results confirmed similarity between powders and ceramics, where dominant phase is BaFe12O19 and a small amount of an apparent BaFe2O4 impurity phase was formed at lower calcination temperature. The impurity BaFe2O4 phase is the main reason for decreasing powder magnetization. The maximum dielectric constant of 100 (at 10 kHz) and maximum remanent polarization, remanent magnetization and saturation magnetization of 0.46 ?C/cm2, 47.37 emu/g and 79.96 emu/g, respectively, were obtained in the barium ferrite ceramics prepared from the powder calcined at 1100?C. This research could be the basis for the study of single-phase multiferroic materials and the development of multi-order electronic devices.
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煅烧温度对钡铁氧体陶瓷结构和多铁性质的影响
本文采用溶胶-凝胶法合成了钡铁氧体粉末,在不同温度下煅烧,并在此基础上制备了相应的陶瓷。研究了煅烧温度对BaFe12O19陶瓷结构、磁性、介电和多铁性的影响。XRD结果证实了粉末与陶瓷的相似性,主要相为BaFe12O19,在较低的煅烧温度下形成少量明显的BaFe2O4杂质相。杂质bafe2o4相是导致粉末磁化强度下降的主要原因。在1100℃下煅烧制备的钡铁氧体陶瓷的最大介电常数为100(10khz),最大剩余极化、剩余磁化和饱和磁化强度分别为0.46 μ C/cm2、47.37 emu/g和79.96 emu/g。该研究可为单相多铁材料的研究和多阶电子器件的开发奠定基础。
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来源期刊
Processing and Application of Ceramics
Processing and Application of Ceramics MATERIALS SCIENCE, CERAMICS-
CiteScore
1.90
自引率
9.10%
发文量
14
审稿时长
10 weeks
期刊介绍: Information not localized
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