Fabrication of an al2o3-1% ti composite with some characteristics of a biomaterial

IF 1.4 4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Science of Sintering Pub Date : 2022-01-01 DOI:10.2298/sos2204415a
Ruth Alvarez-Carrizal, Elizabeth Refugio-García, R. Garcia, M.F. Hernández, E. Rocha-Rangel
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Abstract

An Al2O3-1 wt.% Ti composite was prepared by powder techniques with the intention of analyzing its mechanical and chemical properties for its possible application as a biomaterial. Alumina was synthesized using the reaction bonding aluminum oxide (RBAO) process. The powders resulting from the milling stage present sizes minor than 1.5 microns. With the help of X-ray diffraction and differential thermal analysis, it was determined that aluminum oxidizes in both solid and liquid states during the RBAO process. It was also found that the alumina formation reaction in this process is completed at 1,100oC. From the measurements of mechanical properties (HV, KIC, E) in the Al2O3-1 wt.% Ti composite, it was determined that these properties are better than the same properties of compact bone. Electrochemical impedance spectroscopy, indicates that additions of 1 wt.% Ti on Al2O3 enhance its corrosion resistance. The bioactivation of a Al2O3-1 wt.% Ti composite was successful using a biomimetic method, because after 21 days, hydroxyapatite begins to proliferate on the surface of the substrate. With all these results it can be commented that it is feasible to use Al2O3-1 wt.% Ti composite in the elaboration of synthetic bone for its application as a biomaterial.
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具有生物材料某些特性的al2o3-1% ti复合材料的制备
采用粉末技术制备了Al2O3-1 wt.% Ti复合材料,并对其力学和化学性能进行了分析,为其作为生物材料的应用奠定了基础。采用反应键合氧化铝(RBAO)工艺合成氧化铝。研磨阶段产生的粉末尺寸小于1.5微米。借助x射线衍射和差热分析,确定了铝在RBAO过程中以固态和液态两种状态氧化。还发现该过程中氧化铝的生成反应在1100℃下完成。通过测量Al2O3-1 wt.% Ti复合材料的力学性能(HV, KIC, E),确定了这些性能优于相同性能的致密骨。电化学阻抗谱分析表明,在Al2O3中添加1 wt.%的Ti能提高其耐蚀性。利用仿生方法,Al2O3-1 wt.% Ti复合材料的生物活化是成功的,因为21天后,羟基磷灰石开始在底物表面增殖。以上结果表明,Al2O3-1 wt.% Ti复合材料作为生物材料应用于人工骨的制备是可行的。
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来源期刊
Science of Sintering
Science of Sintering 工程技术-材料科学:硅酸盐
CiteScore
2.50
自引率
46.70%
发文量
20
审稿时长
3.3 months
期刊介绍: Science of Sintering is a unique journal in the field of science and technology of sintering. Science of Sintering publishes papers on all aspects of theoretical and experimental studies, which can contribute to the better understanding of the behavior of powders and similar materials during consolidation processes. Emphasis is laid on those aspects of the science of materials that are concerned with the thermodynamics, kinetics and mechanism of sintering and related processes. In accordance with the significance of disperse materials for the sintering technology, papers dealing with the question of ultradisperse powders, tribochemical activation and catalysis are also published. Science of Sintering journal is published four times a year. Types of contribution: Original research papers, Review articles, Letters to Editor, Book reviews.
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