Effect of milling time on mechanical properties of anorthite obtained by thermal transformation of Ca-LTA zeolite

Abstract

Anorthite ceramics was fabricated from calcium exchanged Na-LTA zeolite. The powder compacts of Ca-LTA zeolite were sintered at different temperatures ranging between 1100 and 1400?C. It was found that the temperature of 1100?C was sufficiently high to trigger formation of anorthite which stayed stable even at temperature as high as 1400?C. The highest relative density and the lowest open porosity were measured in samples sintered at 1200?C for 3 h. The effect of milling time of Ca-LTA zeolite precursor on density, microstructure and mechanical properties of samples sintered at 1200?C for 3 h was investigated. The particle size refinement appeared to be beneficial in accelerating densification process and improving mechanical properties. The density, compressive strength and hardness of anorthite ceramics obtained from non-milled precursor were measured to be 70.5 %TD, 64 MPa and 1.45 GPa, respectively. On the other side the anorthite ceramics obtained from 24-hour-long milled zeolite precursor had density of 83.9 %TD, compressive strength of 101 MPa and hardness of 3.44 GPa.