Prof.?Dr. Yingjie Zhao, Hui Liu, Chenyu Wu, Zhaohui Zhang, Qingyan Pan, Fan Hu, Prof.?Dr. Ruiming Wang, Dr. Piwu Li, Dr. Xiaowen Huang, Prof.?Dr. Zhibo Li
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引用次数: 176
Abstract
The synthesis of fully conjugated sp2-carbon covalent organic frameworks (COF) is extremely challenging given the difficulty of the formation of very stable carbon-carbon double bonds (-C=C-). Here, we report the successful preparation of a 2D COF (TP-COF) based on triazine as central planar units bridged by sp2-carbon linkers through the -C=C- condensation reaction. High-resolution-transmission electron microscopy (HRTEM) clearly confirmed the tessellated hexagonal pore structure with a pore center-to-center distance of 2 nm. Powder X-ray diffraction (PXRD) together with structural simulations revealed an AA stacking mode of the obtained layered structure. TP-COF turned out to be an excellent semiconductor material with a LUMO energy of −3.23 eV and a band gap of 2.36 eV. Excitingly, this novel sp2-carbon conjugated TP-COF exhibited unprecedented coenzyme regeneration efficiency and can significantly boost the coenzyme-assisted synthesis of l-glutamate to a record-breaking 97 % yield within 12 minutes.
期刊介绍:
Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.