S. Sukenaga, R. Ikoma, M. Tashiro, Y. Chiba, S. Kawanishi, H. Shibata
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引用次数: 0
Abstract
The effect of alumina addition on the viscosity of silicate melts is strongly related to the type of non-framework cations; however, the origin of these interactions is not well understood. In this study, we measured the viscosity change in selected alkali disilicate (R2O·2SiO2, R: Na or Li) melts by varying the AlO1.5/SiO2 molar ratio (AlO1.5 = 0–16.8 mol%) within the 1373–1823 K temperature range. We observed that as the molar ratio increased, sodium silicate viscosity increased, whereas lithium silicate viscosity was not affected. Aluminum-27 nuclear magnetic resonance spectra of the quenched glasses indicated that the aluminum cations in both types of alkali silicate melts were mostly present as AlO4 tetrahedra. In contrast to sodium-containing systems, the shear strain on the AlO4 tetrahedron was greater for lithium aluminosilicate glass. Our findings indicated that the degree of shear strain on AlO4 plays an essential role in controlling the viscosity of aluminosilicate systems.
期刊介绍：
High Temperatures – High Pressures (HTHP) is an international journal publishing original peer-reviewed papers devoted to experimental and theoretical studies on thermophysical properties of matter, as well as experimental and modelling solutions for applications where control of thermophysical properties is critical, e.g. additive manufacturing. These studies deal with thermodynamic, thermal, and mechanical behaviour of materials, including transport and radiative properties. The journal provides a platform for disseminating knowledge of thermophysical properties, their measurement, their applications, equipment and techniques. HTHP covers the thermophysical properties of gases, liquids, and solids at all temperatures and under all physical conditions, with special emphasis on matter and applications under extreme conditions, e.g. high temperatures and high pressures. Additionally, HTHP publishes authoritative reviews of advances in thermophysics research, critical compilations of existing data, new technology, and industrial applications, plus book reviews.
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