Selective Molecular Absorption from Low Molecular Weight Mixed Solution to a Polymer P4MP1 Film

A. Chiba, R. Akiyama
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引用次数: 0

Abstract

Recently isotactic poly(4methyl1pentene) (P4MP1) has been found to selectively absorb long-chain alkanes from alkane mixed systems. In this article, we introduce the idea of this study from the pressure-temperature phase diagram. We also show that such selective absorption characteristics can be explained from a simple model, namely Asakura-Oosawa theory, and the relationship with molecular recognition is explained. [host-guest structures, selective absorption, Asakura-Oosawa theory, molecular recognition, melting curve maximum, P4MP1, PMP, SPS]
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低分子量混合溶液对聚合物P4MP1膜的选择性分子吸收
最近发现等规聚(4甲基1戊烯)(P4MP1)对烷烃混合体系中的长链烷烃具有选择性吸附作用。本文从压力-温度相图的角度介绍了本研究的思路。我们还表明,这种选择性吸收特性可以用一个简单的模型来解释,即Asakura-Oosawa理论,并解释了与分子识别的关系。[主客体结构,选择性吸收,Asakura-Oosawa理论,分子识别,熔化曲线最大值,P4MP1, PMP, SPS]
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9
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Foreword 琉球大学 理学部 物質地球科学科物理系 多重自由度相関研究室(物性物理学) ダイヤモンドアンビルセル中の物質の高温高圧その場熱物性測定 High-Pressure Synthesis and In-Situ Physical Property Measurement Using Boron-Doped Diamond 高圧バイオサイエンスという異分野交流
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