Synthesis and Evaluation of CQC-1—An Oil Field Scale Inhibitor

Qi Cao, Xintong Li, X. Wang, Song Wang
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Abstract

Most of the oil wells enter the middle and late stages of extraction. After one oil extraction, water injection is needed for secondary extraction. With a large amount of calcium and magnesium ions in the water, which is easy to form a large amount of insoluble scale, its formed barium sulfate and strontium sulfate scale are more difficult to handle than carbonate scale. In order to reduce the difficulty of oil production work, this paper mainly targeted the sulfate scale for experiments, and prepared the scale retardant agent CQC-1. Through orthogonal experimental screening, the mass ratio of itaconate acid:methacrylic acid:AMPS:sodium acrylic sulfonate was 2:1:1:1, increase the amount of evocating agent was 8% and the reaction time was 4h, the sulfate scale inhibitor synthesized at the temperature of 80 ̊C had the best performance. Using scale resistance rate, degradation and salt-resistance, the experimental results showed that the scale resistance rate of CQC-1 reached 90.46%. In the four-week degradation experiment, the degradation rate reached over 71% and was maintained by 80.65% at 150 ̊C, while the scale resistance rate still reached 80.35% in simulated saline. It has excellent scale resistance, temperature resistance, saltresistance and degradation, and has good development prospects.
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油田阻垢剂cqc -1的合成与评价
大部分油井已进入开采中后期。一次抽油后,需要注水进行二次抽油。水中含有大量的钙、镁离子,容易形成大量的不溶性水垢,其形成的硫酸钡、硫酸锶水垢比碳酸盐水垢更难处理。为了降低采油工作的难度,本文主要针对硫酸盐结垢进行实验,制备了CQC-1型阻垢剂。通过正交实验筛选,衣康酸:甲基丙烯酸:AMPS:丙烯酸磺酸钠的质量比为2:1:1:1,再现剂添加量为8%,反应时间为4h,在80℃合成的硫酸盐阻垢剂性能最佳。实验结果表明,CQC-1的阻垢率达到90.46%。在4周的降解实验中,降解率达到71%以上,在150℃时,降解率维持在80.65%,而在模拟盐水中,阻垢率仍达到80.35%。具有优良的耐垢、耐温、耐盐和降解性能,具有良好的发展前景。
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