Developing a one-part geopolymer cement containing iron ore tailings from Minas Gerais state in Brazil

Ana Beatriz Moreira Silveira, D. Mazzinghy, Ricardo Augusto Martins Figueired
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Abstract

The growing perspective of mining tailings volume worldwide takes to a necessity of developing sustainable solutions to apply the concept of circular economy. Meanwhile, ordinary Portland cement (OPC) is the most consumed construction material globally, and its considerable CO2 emission abundantly contributes to greenhouse effect. Geopolymers are environmentally friendly materials that can be used as a sustainable alternative to OPC. This study proposes the development of a geopolymer cement containing iron ore tailings (IOT) and investigates the influence of the water/solid (W/S) ratio on their uniaxial compressive strength (UCS). The best result had a W/S ratio of 0.37 and achieved strength of 62.7 MPa after 28 days curing at room temperature, which is considerable higher than the required in the worldwide OPC standards. Also, the binder in this study has higher compressive strength after one day of cure than the regular OPC should have in 28 days of cure, showing high early strength. The result can be optimized for better economic viability in the future and shows that IOT has potential to be applied as filler in geopolymer cements.
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开发一种含巴西米纳斯吉拉斯州铁矿尾矿的单组分地聚合物水泥
随着世界范围内尾矿量的不断增长,有必要开发可持续的解决方案,以应用循环经济的概念。同时,普通硅酸盐水泥(OPC)是全球消耗最多的建筑材料,其可观的CO2排放量极大地加剧了温室效应。地聚合物是一种环保材料,可以作为OPC的可持续替代品。本研究提出了一种含铁矿尾矿的地聚合物水泥(IOT)的开发,并研究了水固比(W/S)对其单轴抗压强度(UCS)的影响。室温固化28 d后,最佳W/S比为0.37,强度达到62.7 MPa,大大高于世界OPC标准的要求。同时,本研究的粘结剂在1天固化后的抗压强度高于常规OPC在28天固化后的抗压强度,显示出较高的早期强度。该结果可以在未来优化以获得更好的经济可行性,并表明物联网有潜力应用于地聚合物水泥的填料。
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审稿时长
12 weeks
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