Adsorption of Copper (II) Ions in Aqueous Solution by a Natural Mouka Smectite and an Activated Carbon Prepared from Kola Nut Shells by Chemical Activation with Zinc Chloride (ZnCl2)

Phil Lewis Mpampoungou Langama, J. Anguilè, Albert Novy Messi Me Ndong, Adam Bouraima, C. Bissielou
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Abstract

The aim of this work was to test the adsorption efficiency of copper (II) ions in an aqueous solution on Natural Smectite (NS) and Activated Carbon (AC). The experiments carried out in batch mode made it possible to determine the stirring time, the adsorbent mass, the pH, the initial concentration of copper (II) ions, the isotherms and the adsorption kinetics. It appears that the stirring time was 15 minutes for the AC and 20 minutes for the NS. The adsorption was at maximum for the two adsorbents at optimum pH of 3.5 for a mass of 0.05 g each. The quantity of copper (II) ions adsorbed was 26.6 mg/L for NS and 36.6 mg/g for AC of a concentration of 600 mg/L each. The Langmuir isotherm was the one that best described the adsorption process for the two adsorbents. The adsorption kinetics obtained was that of the pseudo second-order for our two adsorbents. The results obtained showed that these two adsorbents were effective for the adsorption of copper (II) ions in an aqueous solution. (II) Ions Aqueous Solution a Natural and an Activated Carbon Prepared from Kola Nut Shells by Chemical Activation with Zinc Chloride (ZnCl 2 ).
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天然蒙脱石和可乐果壳活性炭对水溶液中铜(II)离子的吸附
研究了天然蒙脱石(NS)和活性炭(AC)对水溶液中铜(II)离子的吸附效率。在间歇式模式下进行的实验可以确定搅拌时间,吸附剂质量,pH,铜(II)离子的初始浓度,等温线和吸附动力学。结果表明,AC搅拌时间为15分钟,NS搅拌时间为20分钟。两种吸附剂在最适pH为3.5,质量为0.05 g时吸附效果最佳。当浓度为600 mg/L时,NS和AC对铜(II)离子的吸附量分别为26.6 mg/L和36.6 mg/g。Langmuir等温线最能描述两种吸附剂的吸附过程。得到的两种吸附剂的吸附动力学为准二级动力学。结果表明,这两种吸附剂对铜(II)离子在水溶液中的吸附效果良好。(二)以可乐果壳为原料,用氯化锌(ZnCl - 2)化学活化制备离子水溶液和活性炭。
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