Surface Effect of Silica Nano-Particles with Different Size on Thermotropic Liquid Crystalline Polyester Composites

Hiroki Fukatsu, Masaaki Kuno, Y. Matsuda, S. Tasaka
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引用次数: 7

Abstract

Interface properties of nano-silica/thermotropic liquid crystalline polyesters (TLCP) composites were investigated by X-ray diffraction analysis and differential scanning calorimetory. The crystallinity of TLCP in the composites drastically decreased with an increase of nano-silica content, depending on the surface area of the silica particles. Little size effects (40 - 400 nm) in the particles and strong interaction between silica surface and the C=O moieties of TLCP were observed by IR analysis. The glass transition temperature of TLCP (。C higher than that in bulk.
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不同粒径纳米二氧化硅在热致液晶聚酯复合材料上的表面效应
采用x射线衍射分析和差示扫描量热法研究了纳米二氧化硅/热致液晶聚酯(TLCP)复合材料的界面性能。随着纳米二氧化硅含量的增加,复合材料中TLCP的结晶度急剧下降,这取决于二氧化硅颗粒的表面积。红外光谱分析发现,在40 ~ 400 nm范围内,TLCP的粒径效应很小,而二氧化硅表面与TLCP的C=O基团之间存在很强的相互作用。TLCP的玻璃化转变温度。C比散装高。
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