{"title":"The Interaction of Deuteroporphyrin IX and its Dimethyl Ester with Oligoethylene Glycols","authors":"T. K. Rocheva, D. V. Belykh","doi":"10.6060/mhc213705r","DOIUrl":null,"url":null,"abstract":"The esterification of carboxyl groups of deuteroporphyrin IX and transesterification of ester groups of dimethyl ester of deuteroporphyrin IX with di-, tetra-, hexaethylene glycols were studied. It is shown, that depending on the oligoethylene glycol and the reaction conditions used, both derivatives with two polyester moieties in the molecule (one for each propionate substituent) and derivatives with one polyester moiety linking the propionate substituents of por-phyrin can be obtained.","PeriodicalId":18090,"journal":{"name":"Macroheterocycles","volume":null,"pages":null},"PeriodicalIF":1.0000,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macroheterocycles","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.6060/mhc213705r","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The esterification of carboxyl groups of deuteroporphyrin IX and transesterification of ester groups of dimethyl ester of deuteroporphyrin IX with di-, tetra-, hexaethylene glycols were studied. It is shown, that depending on the oligoethylene glycol and the reaction conditions used, both derivatives with two polyester moieties in the molecule (one for each propionate substituent) and derivatives with one polyester moiety linking the propionate substituents of por-phyrin can be obtained.
期刊介绍：
The journal is a forum for the specialists investigating macroheterocyclic compounds. It publishes original experimental and theoretical works (full papers and short communications) and reviews on synthesis, structural characterization, physical and coordination chemistry as well as practical application of macroheterocycles.
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