Spectroscopic characteristics of Nd 3+ -doped yttrium lanthanum oxide trans parent ceramics

Pub Date : 2006-11-09 DOI:10.7498/aps.55.6414
Ding Jun, Yang Qiu-hong, Tang Zai-feng, Xu Jun, Su Liang-Bi
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Abstract

Nd 3+ -doped Y 2-2 x La 2 x O 3 ( x =0.08) transparent ceramics were fabricated by conventional fabrication process. Spectroscopic properties of the samples were investigated. The absorption band of Nd 3+ : Y 1.84 La 0.16 O 3 was broad covering the wavelength range 780—850 nm. When doped with 1.5at% Nd 3+ , the cross sections of the sample at 820 nm and laser diode pumped 808 nm were 1.81×10 -20 cm 2 and 1.54×10 -20 cm 2 , respectively. The strongest emission peak of the sample was centered at 1078 nm with long fluorescent lifetime, broad emission bandwidth and high quantum efficiency. Because of the additive La 2 O 3 , the spectroscopic quality parameter ( X Nd ) of matrix was decreased from 1.6 to 0.46, thus the fluorescence branch ratio of 4 F 3/2 — 4 I 11/2 transition was increased to 56.82%. These properties of Nd 3+ : Y 1.84 La 0.16 O 3 transparent ceramic are benefitial to achieve high efficient laser output and ultrashort modelocked pulse.
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Nd - 3+掺杂氧化钇镧透明陶瓷的光谱特性
采用常规工艺制备了Nd 3+掺杂y2 -2 × l2 × o3 (x =0.08)透明陶瓷。对样品的光谱特性进行了研究。Nd 3+: y1.84 la0.16 o3的吸收带较宽,覆盖780 ~ 850 nm的波长范围。当掺1.5at% Nd 3+时,样品在820 nm和激光二极管泵浦808 nm处的截面分别为1.81×10 -20 cm 2和1.54×10 -20 cm 2。样品的最强发射峰集中在1078 nm处,荧光寿命长,发射带宽宽,量子效率高。由于添加了la2o3,使基体的光谱质量参数(X Nd)从1.6降低到0.46,使4f3 /2 - 4i11 /2跃迁的荧光支比提高到56.82%。Nd 3+: y1.84 la0.16 o3透明陶瓷的这些特性有利于实现高效的激光输出和超短锁模脉冲。
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