Spectroscopic characteristics of Nd 3+ -doped yttrium lanthanum oxide trans parent ceramics

Ding Jun, Yang Qiu-hong, Tang Zai-feng, Xu Jun, Su Liang-Bi
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Abstract

Nd 3+ -doped Y 2-2 x La 2 x O 3 ( x =0.08) transparent ceramics were fabricated by conventional fabrication process. Spectroscopic properties of the samples were investigated. The absorption band of Nd 3+ : Y 1.84 La 0.16 O 3 was broad covering the wavelength range 780—850 nm. When doped with 1.5at% Nd 3+ , the cross sections of the sample at 820 nm and laser diode pumped 808 nm were 1.81×10 -20 cm 2 and 1.54×10 -20 cm 2 , respectively. The strongest emission peak of the sample was centered at 1078 nm with long fluorescent lifetime, broad emission bandwidth and high quantum efficiency. Because of the additive La 2 O 3 , the spectroscopic quality parameter ( X Nd ) of matrix was decreased from 1.6 to 0.46, thus the fluorescence branch ratio of 4 F 3/2 — 4 I 11/2 transition was increased to 56.82%. These properties of Nd 3+ : Y 1.84 La 0.16 O 3 transparent ceramic are benefitial to achieve high efficient laser output and ultrashort modelocked pulse.
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Nd - 3+掺杂氧化钇镧透明陶瓷的光谱特性
采用常规工艺制备了Nd 3+掺杂y2 -2 × l2 × o3 (x =0.08)透明陶瓷。对样品的光谱特性进行了研究。Nd 3+: y1.84 la0.16 o3的吸收带较宽,覆盖780 ~ 850 nm的波长范围。当掺1.5at% Nd 3+时,样品在820 nm和激光二极管泵浦808 nm处的截面分别为1.81×10 -20 cm 2和1.54×10 -20 cm 2。样品的最强发射峰集中在1078 nm处,荧光寿命长,发射带宽宽,量子效率高。由于添加了la2o3,使基体的光谱质量参数(X Nd)从1.6降低到0.46,使4f3 /2 - 4i11 /2跃迁的荧光支比提高到56.82%。Nd 3+: y1.84 la0.16 o3透明陶瓷的这些特性有利于实现高效的激光输出和超短锁模脉冲。
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来源期刊
CiteScore
1.60
自引率
0.00%
发文量
9103
期刊介绍: Journal of the Chinese Ceramic Society was founded in 1957 and published scientific research papers in Chinese or English for Chinese and English academic journals (16 journals). Journal of silicate is a core journal in Chinese, double-effect journal, Chinese excellent scientific journals, 100 outstanding Chinese academic journals, Chinese Association of Science and Technology excellent scientific journals (Category B).
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