Synthesis, Crystal Structure, and Hirshfeld Surface Analysis of a Dinuclear Copper Complex with Pyrazole

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2023-11-01 DOI:10.1134/S1070328422600498
Z. Q. Li, J. J. Guo, C. Feng
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Abstract

A new dinuclear complex, [Cu2I2(Pz)2(Phen)2] (I) was synthesized by solution method based on HPz, Phen and CuI2, where HPz is pyrazole and Phen is 1,10-phenanthroline, respectively. On this basis, complex I was characterized by IR spectra and analyzed by X-ray diffraction (CCDC no. 2169849). We also studied Hirshfeld surface of the title complex.

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吡唑双核铜配合物的合成、晶体结构和Hirschfeld表面分析
以HPz、Phen和CuI2为原料,采用溶液法合成了新型双核配合物[Cu2I2(Pz)2(Phen)2](I),其中HPz分别为吡唑,Phen为1,10-菲罗啉。在此基础上,用红外光谱对配合物I进行了表征,并用X射线衍射(CCDC no.2169849)进行了分析。我们还研究了标题复合体的赫什菲尔德曲面。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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