Adsorption and corrosion inhibition characteristics of some organic molecules containing methoxy phenyl moiety on mild steel in hydrochloric acid solution

Doddahosuru M. Gurudatt , Kikkeri N. Mohana , Harmesh C. Tandon
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引用次数: 13

Abstract

The influence of three newly synthesized molecules on the corrosion inhibition of mild steel in acid media is studied. From Tafel slopes, it is evident that the anodic reaction is more polarized. Impedance study reveals that the increase in Rct values can be attributed to the formation of a protective film and the decrease in Cdl values is due to an increase in the thickness of the electrical double layer. Total energy, EHOMO and softness are in the order of 3-MPTT > 4-AMTT > 3-MAH and dipole moment, ELUMO, energy gap, ionization potential and hardness are in the order of 3-MPTT < 4-AMTT < 3-MAH.

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一些含甲氧基苯基的有机分子在软钢上在盐酸溶液中的吸附和缓蚀特性
研究了三种新合成的分子对低碳钢在酸性介质中缓蚀性能的影响。从Tafel斜率可以明显看出,阳极反应更加极化。阻抗研究表明,Rct值的增加可归因于保护膜的形成,而Cdl值的降低是由于双电层厚度的增加。总能量、EHOMO和柔软度在3-MPTT>;4-AMTT>;3-MAH和偶极矩、ELUMO、能隙、电离势和硬度的顺序为3-MPTT<;4-AMTT<;3个小时。
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