Anion binding by a binuclear Cu(II) polyamine macrocyclic complex

Carla Bazzicalupi, Andrea Bencini, Antonio Bianchi, Lucia Borsari, Samuele Ciattini, Andrea Danesi, Claudia Giorgi, Federica Lombardini, Barbara Valtancoli
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双核Cu(II)多胺大环配合物与阴离子的结合
双位大环配体1,4,7,10,19,22,25,28-八氮杂-13,16,31,34-四氧杂环十六碳烷(L)在水溶液中形成非常稳定的单核和双核Cu2+配合物。报道了这些配合物的稳定常数。在固态中,双核配合物产生{[(Cu2L)Cl]⊃Cl(H2O)}(ClO4)2化合物,其中Cu2+促进的阴离子结合的直接和间接活化,以及该金属阳离子对阴离子结合的结构效应,协同参与聚合物包合物的组装。
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