High temperature resistance studies of thin nickel foils exposed to hydrogen and oxygen

B.A. Quimby , S.R. Shatynski
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Abstract

Resistance measurements were performed on thin nickel foils exposed to argon-oxygen gas mixtures at elevated temperatures. The resistance initially increased very rapidly then at oxygen pressures less than 0.08 atm, the resistance change decreased substantially before slowly increasing. At higher oxygen pressures no decrease in the resistance change occurred. These results are interpreted in light of hydrogen-oxygen-nickel interactions which occur as a result of hydrogen dissolution in nickel prior to oxidation The hydrogen originates from long-term hydrogen anneals prior to the oxidation.

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暴露于氢气和氧气中的薄镍箔的耐高温性研究
在暴露于高温下的氩-氧气体混合物的薄镍箔上进行电阻测量。电阻最初增加得非常快,然后在小于0.08atm的氧气压力下,电阻变化在缓慢增加之前显著降低。在较高的氧气压力下,电阻变化没有减少。这些结果是根据氢-氧-镍相互作用来解释的,这种相互作用是氢在氧化前溶解在镍中的结果。氢来源于氧化前的长期氢退火。
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