The nature of surface chemical heterogeneities of graphitized carbon black

L. Campanella , A. Di Corcia , R. Samperi , A. Gambacorta
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引用次数: 25

Abstract

Experimental evidence is presented for the existence of quinone, aromatic ether, carboxylic acid and phenol groups on the surface of a graphitized carbon black (GCB), that is P-33 (2700°C). This evidence has been achieved by using polarographic analysis of a slurry of GCB particles.

Polarographic analysis has been also performed for ungraphitized P-33.

By comparison, it appears that the heating at 2700°C does not remarkably change the nature and the amount of chemical groups chemically bound to the surface of the carbon black.

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石墨化炭黑表面化学不均匀性的性质
实验证明了石墨化炭黑(GCB)P-33(2700°C)表面存在醌、芳香醚、羧酸和酚基团。这一证据是通过使用GCB颗粒浆料的极谱分析获得的。还对未硫化的P-33进行了极谱分析。相比之下,2700°C下的加热似乎不会显著改变化学结合到炭黑表面的化学基团的性质和数量。
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