Silicon assistant carbothermal reduction for SiC powders

Kezhi Li, Jian Wei, Hejun Li, Chuang Wang, Gengsheng Jiao
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引用次数: 12

Abstract

The silicon assistant method to increase the reaction yield of carbothermal reduction of silica at a lower temperature is reported. The effect of silicon on the carbothermal reduction process has been investigated in detail. Compared with traditional reduction, the introduction of silicon can change the reaction path and further increase the conversion of silicon carbide at a lower temperature. It is considered that the assistant reduction consists of three steps: vaporizing and melting of silicon, formation of silicon monoxide, and synthesis of silicon carbide. The morphology of the synthesized SiC powders through the silicon assistant method can be affected apparently by the experimental temperature.

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碳化硅粉末的硅辅助碳热还原
报道了一种在较低温度下提高二氧化硅碳热还原反应产率的硅辅助方法。详细研究了硅对碳热还原过程的影响。与传统还原相比,硅的引入可以改变反应路径,在较低的温度下进一步提高碳化硅的转化率。认为辅助还原包括三个步骤:硅的蒸发和熔化、一氧化硅的形成和碳化硅的合成。实验温度对硅辅助法合成的SiC粉体的形貌有明显的影响。
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