Reactions between perchlorate salts and tetrahydrofuran

Y. Eckstein, P. Dreyfuss
{"title":"Reactions between perchlorate salts and tetrahydrofuran","authors":"Y. Eckstein,&nbsp;P. Dreyfuss","doi":"10.1016/0022-1902(81)80431-9","DOIUrl":null,"url":null,"abstract":"<div><p>Reactions between tetrahydrofuran (THF) and 22 different perchlorate salts, most often in the presence of organic halides were studied. The use of the organic halides including acetyl, benzoyl and substituted allyl chlorides aided in arranging the perchlorates according to their ability to give good yields of tertiary oxonium ion and polymer from THF. The approximate order, based on the yield of poly(tetrahydrofuran) obtained after 24 hr was Ag<sup>+</sup>, Hg<sup>2+</sup> &gt; Pb<sup>2+</sup>, Tl<sup>3+</sup> &gt; Fe<sup>3+</sup>, Al<sup>3+</sup>, Na<sup>+</sup>, Fe<sup>2+</sup> &gt; Cr<sup>3+</sup>, Mn<sup>2+</sup>, Ni<sup>2+</sup>, Cu<sup>2+</sup>, Co<sup>2+</sup>, Cd<sup>2+</sup> ⪢ Ce<sup>3+</sup>, Mg<sup>2+</sup>, Ca<sup>2+</sup>, Ba<sup>2+</sup>, Zn<sup>2+</sup>, Li<sup>+</sup>, K<sup>+</sup>, NH<sub>4</sub><sup>+</sup> = 0. Only Ag<sup>+</sup> and Hg<sup>2+</sup> perchlorates gave polymer when allylhalides were used. With one other perchlorates the order of reactivity of the halide was acetyl &gt; benzoyl ⪢ allyl = 0.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 1","pages":"Pages 23-27"},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80431-9","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inorganic and Nuclear Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022190281804319","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3

Abstract

Reactions between tetrahydrofuran (THF) and 22 different perchlorate salts, most often in the presence of organic halides were studied. The use of the organic halides including acetyl, benzoyl and substituted allyl chlorides aided in arranging the perchlorates according to their ability to give good yields of tertiary oxonium ion and polymer from THF. The approximate order, based on the yield of poly(tetrahydrofuran) obtained after 24 hr was Ag+, Hg2+ > Pb2+, Tl3+ > Fe3+, Al3+, Na+, Fe2+ > Cr3+, Mn2+, Ni2+, Cu2+, Co2+, Cd2+ ⪢ Ce3+, Mg2+, Ca2+, Ba2+, Zn2+, Li+, K+, NH4+ = 0. Only Ag+ and Hg2+ perchlorates gave polymer when allylhalides were used. With one other perchlorates the order of reactivity of the halide was acetyl > benzoyl ⪢ allyl = 0.

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
高氯酸盐与四氢呋喃之间的反应
研究了四氢呋喃(THF)与22种不同的高氯酸盐之间的反应,大多数是在有机卤化物存在的情况下进行的。使用有机卤化物,包括乙酰、苯甲酰和取代的烯丙基氯化物,有助于根据高氯酸盐从四氢呋喃中获得叔氧离子和聚合物的能力来安排高氯酸盐。根据24h后聚四氢呋喃的产率,大致顺序为Ag+, Hg2+ >Pb2+, Tl3+ >Fe3+, Al3+, Na+, Fe2+ >Cr3 + Mn2 + Ni2 +, Cu2 +, Co2 + Cd2 +⪢Ce3 +, Mg2 + Ca2 +,菲律宾媒体+ Zn2 + +, K + NH4 + = 0。当使用烯丙基卤化物时,只有Ag+和Hg2+高氯酸盐产生聚合物。卤化物与另一种高氯酸盐的反应活性顺序为乙酰;苯甲酰⪢烯丙基= 0。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Ligand exchange reactions between copper(II)- and nickel(II)-chelates of different sulfur- and selenium-containing ligands Subject index Errata Editorial Board Errata
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1