Chiral crystallization of anti-dodecaisopropyltricyclo-[4.2.00.0(2,5)] octasilane.

Enantiomer Pub Date : 2002-07-01 DOI:10.1080/10242430212882
R. Tanaka, S. Kyushin, M. Unno, H. Matsumoto
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引用次数: 5

Abstract

The aim of this article is to describe the results of our investigation on the chiral crystallization of anti-tricyclic ladder polysilane, anti-dodecaisopropyltricyclo [4.2.0.0(2,5)] octasilane (1). In solid state, the silicon framework of 1 adopts twisted conformation in which the Si4 rings are puckered in the same direction. Crystallization of 1 afforded a large conglomerate crystal in high yield. X-ray crystallography revealed that the crystal consists of either right-handed (P) or left-handed (M) molecules. The ultraviolet and circular dichroism spectra of the chiral crystals of 1 reveal two absorption bands in the 400-250 nm region.
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反十二烷基异丙基三环-[4.2.00.0(2,5)]辛烷的手性结晶。
本文的目的是描述我们对反三环梯形聚硅烷,反十二异丙基三环[4.2.0.0(2,5)]辛硅烷(1)的手性结晶的研究结果。在固体状态下,1的硅骨架采用扭转构象,其中Si4环沿同一方向折叠。1的结晶产生了大的砾岩晶体,产量高。x射线晶体学显示晶体由右旋(P)或左旋(M)分子组成。1的手性晶体的紫外和圆二色光谱在400-250 nm区域显示出两条吸收带。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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