Nongyue He , Zuhong Lu , Chunwei Yuan , Jianming Hong , Chun Yang , Shulin Bao , Qinhua Xu
{"title":"Effect of trivalent elements on the thermal and hydrothermal stability of MCM-41 mesoporous molecular materials","authors":"Nongyue He , Zuhong Lu , Chunwei Yuan , Jianming Hong , Chun Yang , Shulin Bao , Qinhua Xu","doi":"10.1016/S0968-5677(98)00073-X","DOIUrl":null,"url":null,"abstract":"<div><p>Effect of trivalent elements on the thermal and hydrothermal stability of MCM-41 mesoporous molecular sieve materials has been investigated. Al(III) decreases the thermal and hydrothermal stability of MCM-41 materials, whereas La(III) and Fe(III), especially Fe(III), can improve the thermal and hydrothermal stability. Benzene adsorption and IR spectra suggested that thick channel wall and the fewer structural defect sites in MCM-41 would enhance the thermal and hydrothermal stability of MCM-41.</p></div>","PeriodicalId":22050,"journal":{"name":"Supramolecular Science","volume":"5 5","pages":"Pages 553-558"},"PeriodicalIF":0.0000,"publicationDate":"1998-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0968-5677(98)00073-X","citationCount":"12","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Supramolecular Science","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S096856779800073X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 12
Abstract
Effect of trivalent elements on the thermal and hydrothermal stability of MCM-41 mesoporous molecular sieve materials has been investigated. Al(III) decreases the thermal and hydrothermal stability of MCM-41 materials, whereas La(III) and Fe(III), especially Fe(III), can improve the thermal and hydrothermal stability. Benzene adsorption and IR spectra suggested that thick channel wall and the fewer structural defect sites in MCM-41 would enhance the thermal and hydrothermal stability of MCM-41.