Study on Development and Evaluation of Metal Ion Separation Systems Based on Complexation and Liquid-liquid Transfer

N. Hirayama
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Abstract

The author has studied on solvent extraction separation of metal ions, focusing on development and separation ability analysis of various polydentate ligands as extractants, and functional analysis of ionic liquids (ILs) as novel extraction solvents. This paper presents an outline of the authors’ fruits of research on separation ability of pendant-arm-type polydentate ligands and sulfonamide-type polydentate ligands, evaluation of charge of extracted species in IL chelate extraction, development of IL triphasic extraction system, and possible use of hydrophilic ILs as salting-out phase separation agent.
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基于络合和液-液转移的金属离子分离体系的开发与评价研究
笔者对金属离子的溶剂萃取分离进行了研究,重点研究了各种多齿配体作为萃取剂的开发和分离能力分析,以及离子液体作为新型萃取溶剂的功能分析。本文综述了垂臂型多齿配体和磺胺型多齿配体的分离能力、IL螯合萃取中被萃取物的电荷评价、IL三相萃取体系的开发以及亲水性IL作为盐析相分离剂的可能性等方面的研究成果。
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