High-temperature deformation of a geopolymer.

F. Gutiérrez-Mora, A. Domínguez-Rodríguez, K. Goretta, Dileep Singh, J. Routbort, G. C. Lukey, J. Deventer
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Abstract

Compressive creep under constant load (stresses of 0.5-10 MPa) of a geopolymer was investigated between 975 and 1025°C. The geopolymer was derived from Class F fly ash, kaolin, granulated blast furnace slag, sodium and potassium silicate and carbonate. Silicate-based aggregates constituted 48% of the total mass. The temperature range of testing was small because of limited plasticity below 975°C and decomposition above 1050°C. The maximum accumulated strain was 15%. A regime of true steady-state creep probably did not exist. Damage occurred at aggregate/geopolymer interfaces, induced in part by the stress concentrations there. Microstructural evolution was also observed, with calcium segregating from the geopolymer matrix toward the aggregates interfaces. The tests revealed that the geopolymer supported modest compressive stresses and exhibited significant strain or pseudo-plasticity.
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地聚合物的高温变形。
研究了一种地聚合物在975 ~ 1025℃的恒载(应力0.5 ~ 10mpa)下的压缩蠕变特性。该地聚合物由F级粉煤灰、高岭土、粒状高炉矿渣、硅酸钠钾和碳酸盐等原料制备而成。硅酸盐基团聚体占总质量的48%。试验温度范围小,因为975℃以下塑性有限,1050℃以上分解。最大累积应变为15%。真正的稳态蠕变状态可能并不存在。损伤发生在骨料/地聚合物界面,部分原因是那里的应力集中。微观结构的演变也被观察到,钙从地聚合物基质向聚集体界面分离。试验表明,地聚合物承受适度的压应力,并表现出显著的应变或伪塑性。
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