{"title":"Comparisons of activation energies for guest escapes from the inner phases of hemicarcerands with varying numbers of bowl-linking groups","authors":"Timothy A. Bobbins, D. Cram","doi":"10.1039/C39950001515","DOIUrl":null,"url":null,"abstract":"The syntheses and characterization of new hemicarcerands 3 and new complexes of 4 are described; the half-lives and activation energies for incarcerated Me2NCHO and Me2NCOMe escaping from the inner phases of 2 and 4 are compared.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950001515","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 8
Abstract
The syntheses and characterization of new hemicarcerands 3 and new complexes of 4 are described; the half-lives and activation energies for incarcerated Me2NCHO and Me2NCOMe escaping from the inner phases of 2 and 4 are compared.
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