IMPROVING THE INTERFACIAL PROPERTIES OF GLASS FIBRE REINFORCED AND UNREINFORCED WASTE SOURCED LOW DENSITY POLYETHYLENE/ACRYLONITRILE BUTADIENE STYRENE/POLYSTYRENE COMPOSITES

J. Sója, V. Sedlařík, P. Kucharczyk, N. Miskolczi
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Abstract

This work is focused on compatibilization of immiscible waste sourced low density polyethylene (LDPE), acrylonitrile butadiene styrene (ABS), and polystyrene (PS) blends by different surface modifying routes. To reach better mechanical properties of the given reused waste blends 20% glass fibre was used. The ratio of waste LDPE/ABS/PS was 3.6/2.0/1.0 both in the presence and absence of glass fibre, while the applied concentration of the surface modifying routes was 1% in each case. Blends of raw materials had been manufactured by two roll mill, and specimens were obtained by the press moulded plates. The properties of samples were studied by mechanical testing. Results show that blending of the three kinds of waste polymers without compatibilizers resulted immiscible blends with poor mechanical properties. This could be significantly improved by the application of the commercial and synthetic surface treatment additives. Generally, favourable properties were found in the presence of 20% glass fibre. Especially AD-1 and AD-2 experimental and commercial γ-aminopropylsilane additives showed the best results.
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提高玻璃纤维增强和非增强垃圾低密度聚乙烯/丙烯腈-丁二烯-苯乙烯/聚苯乙烯复合材料的界面性能
研究了不同表面改性途径对低密度聚乙烯(LDPE)、丙烯腈-丁二烯-苯乙烯(ABS)和聚苯乙烯(PS)共混物的增容作用。为了达到更好的机械性能,使用了20%的玻璃纤维。在不添加玻璃纤维和不添加玻璃纤维的情况下,废LDPE/ABS/PS的比例为3.6/2.0/1.0,表面改性路线的应用浓度均为1%。采用双辊轧机对原料进行了共混,并通过压模制版获得了试样。通过力学试验研究了样品的性能。结果表明,在不添加增容剂的情况下,三种废聚合物共混产生的共混物力学性能较差。这可以通过应用商业和合成的表面处理添加剂来显著改善。一般来说,在20%玻璃纤维的存在下发现了良好的性能。其中AD-1和AD-2是实验用和商用的γ-氨基丙基硅烷添加剂,效果最好。
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