Reevaluation of the temperature dependence of the reactions of Cl+ and HCl+· with H2

Paul R. Kemper, Michael T. Bowers
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引用次数: 3

Abstract

The temperature dependence of the reaction of Cl+ with H2 has been the subject of several recent studies. The interest in this reaction derives mainly from its importance in modeling chlorine chemistry in interstellar clouds. New data on this reaction are reported that suggest the reaction has a weak negative temperature dependence in agreement with recent flow tube studies. Data for the HD and D2 isotopic species show the same trend. New data on the HCl+ + H2 reaction are also reported.

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Cl+和HCl+·与H2反应温度依赖性的再评价
Cl+与H2反应的温度依赖性是最近几项研究的主题。对这个反应的兴趣主要来自于它在模拟星际云中的氯化学中的重要性。据报道,该反应的新数据表明,该反应具有弱的负温度依赖性,与最近的流管研究一致。HD和D2同位素种类的数据显示了相同的趋势。报道了HCl+ + H2反应的新数据。
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Editorial Subject index Author index High resolution accurate mass measurements of FAB-generated ions by use of peak matching and multichannel analyzer techniques. Secondary ion mass spectrometry of low-temperature solids
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