{"title":"Reevaluation of the temperature dependence of the reactions of Cl+ and HCl+· with H2","authors":"Paul R. Kemper, Michael T. Bowers","doi":"10.1016/0020-7381(83)85023-2","DOIUrl":null,"url":null,"abstract":"<div><p>The temperature dependence of the reaction of Cl<sup>+</sup> with H<sub>2</sub> has been the subject of several recent studies. The interest in this reaction derives mainly from its importance in modeling chlorine chemistry in interstellar clouds. New data on this reaction are reported that suggest the reaction has a weak negative temperature dependence in agreement with recent flow tube studies. Data for the HD and D<sub>2</sub> isotopic species show the same trend. New data on the HCl<sup>+</sup> + H<sub>2</sub> reaction are also reported.</p></div>","PeriodicalId":13998,"journal":{"name":"International Journal of Mass Spectrometry and Ion Physics","volume":"51 1","pages":"Pages 11-16"},"PeriodicalIF":0.0000,"publicationDate":"1983-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7381(83)85023-2","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Mass Spectrometry and Ion Physics","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020738183850232","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
Abstract
The temperature dependence of the reaction of Cl+ with H2 has been the subject of several recent studies. The interest in this reaction derives mainly from its importance in modeling chlorine chemistry in interstellar clouds. New data on this reaction are reported that suggest the reaction has a weak negative temperature dependence in agreement with recent flow tube studies. Data for the HD and D2 isotopic species show the same trend. New data on the HCl+ + H2 reaction are also reported.
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