{"title":"Synthesis of Bismuth(III)Neodecanoate and Its Application to Poly(Vinyl Chloride) as a Thermal Stabilizer","authors":"Hongliang Liu, P. Jiang, Kai Zhang, Yuming Dong","doi":"10.1080/03602559.2017.1410848","DOIUrl":null,"url":null,"abstract":"ABSTRACT The bismuth(III)neodecanoate (Bi(Ne)3) was synthesized via the method of co-reaction of bismuth oxide, neodecanoic acid, and acetic anhydride and then characterized by Fourier transform infrared spectroscopy (FTIR) and elemental analysis (EA). The effect of Bi(Ne)3 as a thermal stabilizer on poly(vinyl chloride) (PVC) was assessed by thermal aging test, Congo red test, conductivity measurement, and thermogravimetric analysis, respectively. The results showed that Bi(Ne)3 significantly provided PVC with a good initial color and long-term stability. Bi(Ne)3 played a role in improving the stabilizing efficiency of PVC through absorbing hydrogen chloride (HCl) and displacing labile chlorine atoms in PVC molecular chains. GRAPHICAL ABSTRACT","PeriodicalId":20629,"journal":{"name":"Polymer-Plastics Technology and Engineering","volume":"213 1","pages":"1657 - 1664"},"PeriodicalIF":0.0000,"publicationDate":"2018-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer-Plastics Technology and Engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/03602559.2017.1410848","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Materials Science","Score":null,"Total":0}
引用次数: 1
Abstract
ABSTRACT The bismuth(III)neodecanoate (Bi(Ne)3) was synthesized via the method of co-reaction of bismuth oxide, neodecanoic acid, and acetic anhydride and then characterized by Fourier transform infrared spectroscopy (FTIR) and elemental analysis (EA). The effect of Bi(Ne)3 as a thermal stabilizer on poly(vinyl chloride) (PVC) was assessed by thermal aging test, Congo red test, conductivity measurement, and thermogravimetric analysis, respectively. The results showed that Bi(Ne)3 significantly provided PVC with a good initial color and long-term stability. Bi(Ne)3 played a role in improving the stabilizing efficiency of PVC through absorbing hydrogen chloride (HCl) and displacing labile chlorine atoms in PVC molecular chains. GRAPHICAL ABSTRACT
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